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CHALLENGE
OF MATERIALS



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ALUMINIUM
Aluminium is a strong, lightweight,
silver-white, ductile and malleable, metallic element, symbol Al. It
is the third most abundant element in the Earth's crust and by far
the most abundant metal on Earth. It is an excellent conductor of
electricity and oxidizes easily making it highly resistant to
tarnish. Aluminium comes from the word alumen, which is the Latin
name for alum. Aluminium Sulphate (commonly known as
alum) |
Alum |
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TITANIUM
Titanium is a strong, lightweight,
silver-grey, metallic element which is resistant to corrosion,
symbol Ti. It is the ninth most abundant element in the Earth's
crust, its compounds occur in practically all igneous rocks and
their sedimentary deposits. The element was discovered in 1791 by
English mineralogist William Gregor and was named by German chemist
Martin Klaproth after Titan one of the giants of Greek mythology. It
was not obtained in pure form until 1925. Titanium is the most
bio-compatible of all metals due to its total resistance to attack
by body fluids, high strength and low modulus. Titanium is widely
used for implants, surgical devices, and pacemaker cases. Titanium
replacements for hips and other joints are well established and have
been in use for over 30 years. Advanced coatings are now available
which hasten the bonding of titanium with adjacent
bone. |
Molecular structure of
Titanium |
Titanium is used for its excellent corrosion
and erosion resistance, high heat transfer efficiency, and superior
strength-to-weight ratio. The bio-compatibility and strength of
titanium make it an ideal material for dental posts and other oral
prosthetics. Bone naturally adheres to the surface oxide of titanium
without additional coatings. |
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GLASS
Glass is a transparent or translucent
substance that is physically neither a solid nor a liquid. Although
glass is easily shattered, it is one of the strongest substances
known. It is made by fusing certain types of sand.
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Molecular structure of
Silicone Rubber

Polyethene
Atoms |
POLYETHENE
Polyethene is a tough white, translucent, waxy
thermoplastic (which means it can be repeatedly softened by
heating). Polymer of the gas ethylene (technically called ethene,
C2H4). It is used for packaging, bottles, toys, wood preservation,
electric cable, pipes and tubing. Polyethylene is produced in two
forms: low-density polyethylene, made by high-pressure
polymerization of ethylene gas, and high-density polyethylene, which
is made at lower pressure by using catalysts. This form, first made
1953 by German chemist Karl Ziegler, is more rigid at low
temperatures and softer at higher temperatures than the low-density
type. Polyethylene was first made in the 1930s at very high
temperatures by ICI. In the UK it is better known under the
trademark Polythene. |
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POLYTETRAFLUOROETHYLENE
(PTFE)
PTFE is used in a wide variety of permanent
implants from vascular grafts to coatings on sutures and other
materials. There is a decades long history of use of PTFE: it is
considered to be inert and benign in the body. Some major permanent
implant uses of PTFE are given below. According to the estimates
approximately 85 % by weight of the PTFE resin used for permanent
implants is used for lifesaving implants.
MAJOR IMPLANT APPLICATIONS
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Vascular graft
prostheses
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Surgical patches
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Sewing collar for heart
valves
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Attachment backing for implants
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Knee
ligaments
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Catheter access ports
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Insulator for heart pacing
wires
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Suture coatings
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Ventilation tubes for
infants
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Middle ear prostheses
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POLYESTER
Polyester is a synthetic resin formed by the
condensation of polyhydric alcohols with diabasic acids. Polyesters
are thermosetting plastics used in making sythentic fibres and
constructional plastics. |
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NYLON
Nylon is a synthetic long-chain polymer. Nylon
was the first all-synthesised fibre, made from petroleum, natural
gas, air, and water. It is used in the manufacture of medical
sutures. Nylon fibres are stronger and more elastic than silk and
are relatively insensitive to moisture and
mildew. |
The manufacture of carbon
fibre |
CARBON FIBRE
Carbon fibre is a fine, black, silky filament
of pure carbon produced by heat treatment from a special grade of
Courtelle acrylic fibre and, used for reinforcing plastics. The
resulting composite is very stiff and, weight for weight, has four
times the strength of high-tensile steel. It is used in the
aerospace industry, cars, and electrical and sports
equipment. |
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POLYMETHYLMETHACRYLATE
(PMMA) - PERSPEX
Perspex is the trade name for a clear,
lightweight, tough plastic first produced 1930. It is widely used
for watch glasses, advertising signs, domestic baths, motorboat
windscreens, aircraft canopies, and protective shields. Its chemical
name is polymethylmethacrylate. |
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PLASTICS
Plastics are any of the stable synthetic
materials that are fluid at some stage in their manufacture, when
they can be shaped, and that later set to rigid or semi-rigid
solids. Plastics today are chiefly derived from petroleum. Most are
polymers, made up of long chains of identical molecules. Since
plastics have afforded an economical replacement for ivory in the
manufacture of piano keys and billiard balls, the industrial chemist
may well have been responsible for the survival of the elephant.
Most plastics cannot be broken down by microorganisms, so cannot
easily be disposed of. Incineration leads to the release of toxic
fumes, unless carried out at very high temperatures. Processed by
extrusion, injection-moulding, vacuum-forming, and compression,
plastics emerge in consistencies ranging from hard and inflexible to
soft and rubbery. They replace an increasing number of natural
substances, being lightweight, easy to clean, durable, and capable
of being rendered very strong for example, by the addition of carbon
fibres for building aircraft and other engineering projects.
Thermoplastics soften when warmed, then
re-harden as they cool. Examples of thermoplastics include
polystyrene, a clear plastic used in kitchen utensils or (when
expanded into a 'foam' by gas injection) in insulation and ceiling
tiles; polyethylene (polythene), used for containers and wrapping;
and polyvinyl chloride (PVC), used for drainpipes, floor tiles,
audio discs, shoes, and handbags. Thermosets remain rigid once set,
and do not soften when warmed. They include Bakelite, used in
electrical insulation and telephone receivers; epoxy resins, used in
paints and varnishes, to laminate wood, and as adhesives;
polyesters, used in synthetic textile fibres and, with fibreglass
reinforcement, in car bodies and boat hulls; and polyurethane,
prepared in liquid form as a paint or varnish, and in foam form for
upholstery and in lining materials (where it may be a fire hazard).
One group of plastics, the silicones, are chemically inert, have
good electrical properties, and repel water. Silicones find use in
silicone rubber, paints, electrical insulation materials, laminates,
waterproofing for walls, stain-resistant textiles, and cosmetics.
PolyAmides are widely used for the production of film, sheet, and
injection-moulded articles.
Nylon, the first polyamide, was synthesized in
1934 by Wallace Carothers at the du Pont laboratories in the USA and
was intended to have many of the properties possessed of natural
silk. Although it does have other applications, nylon is known
principally for its applications in the textile field. Nylon yarn,
once it has been stretched during the filament-forming process, has
a combination of properties unique among textile fibres. One of the
most notable is remarkable tensile strength, combined with lightness
in weight and a high degree of resilience. shape-memory
polymers.
Manufactured forms
of plastic |
Shape-memory polymers are plastics that
can be crumpled or flattened and will resume their original
shape when heated. They include trans-polyisoprene and
polynorbornene. The initial shape is determined by heating the
polymer to over 35 to 95 Degrees C and pouring it into a metal
mould. The shape can be altered with boiling water and the
substance solidifies again when its |
temperature falls. Biodegradable plastics are
increasingly in demand: Biopol was developed in 1990. Soil
microorganisms are used to build the plastic in their cells from
carbon dioxide and water (it constitutes 80% of their cell tissue).
The unused parts of the microorganism are dissolved away by heating
in water. The discarded plastic can be placed in landfill sites
where it breaks back down into carbon dioxide and water. It costs
three to five times as much as ordinary plastics to produce. Another
plastic digested by soil microorganisms is polyhydroxybutyrate
(PHB), which is made from
sugar. | |